Patent · US Expired

Chemical vapor deposition of fluorocarbon polymer thin films

US6156435A · kind A · utility

140Cited by
6References
14Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMar 29, 1999
Grant dateDec 5, 2000
Priority date
Expiry dateMar 29, 2019

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10T428/31544
  • WIPO fieldSurface technology, coating
  • WIPO sectorChemistry

Abstract

Provided are methods for forming a fluorocarbon polymer thin film on the surface of a structure. In one method, a monomer gas is exposed to a source of heat having a temperature sufficient to pyrolyze the monomer gas and produce a source of reactive CF.sub.2 species in the vicinity of the structure surface. The structure surface is maintained substantially at a temperature lower than that of the heat source to induce deposition and polymerization of the CF.sub.2 species on the structure surface. In another method for forming a fluorocarbon polymer thin film, the structure is exposed to a plasma environment in which a monomer gas is ionized to produce reactive CF.sub.2 species. The plasma environment is produced by application to the monomer gas of plasma excitation power characterized by an excitation duty cycle having alternating intervals in which excitation power is applied and in which no excitation power is applied to the monomer gas. The monomer gas employed in the methods preferably includes hexafluoropropylene oxide. The monomer gas pyrolysis and plasma excitation methods can be carried out individually, sequentially, or simultaneously. Flexible fluorocarbon polymer thin fi…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.