Patent · US Expired

Method of fabricating a copper damascene structure

US6660639B2 · kind B2 · utility

10Cited by
4References
19Claims
0Family size

Assignee

Inventors

Key dates

Filing dateOct 7, 2002
Grant dateDec 9, 2003
Priority date
Expiry dateOct 7, 2022

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC23F3/00
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

The present invention provides a method of removing copper overlaying a tantalum-based barrier layer during the fabrication of a copper damascene structure having a plurality of copper lines. The method includes providing a chemical-mechanical polishing slurry and polishing the copper layer using the slurry until the tantalum-based barrier layer is exposed. The slurry includes an oxidizing agent that releases free radicals and a non-chelating free radical quencher that retards the corrosion of said copper lines during chemical mechanical polishing. Preferred non-chelating free radical quenchers are ascorbic acid, thiamine, 2-propanol, and alkyl glycols. The present invention also provides copper damascene structures formed according to the method.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.