Patent · US Expired

Post ECP multi-step anneal/H2 treatment to reduce film impurity

US7030016B2 · kind B2 · utility

9Cited by
7References
37Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMar 30, 2004
Grant dateApr 18, 2006
Priority date
Expiry dateMar 30, 2024

Classification

  • Technology area (CPC H)Electricity
  • CPC primaryH01L21/2885
  • WIPO fieldSemiconductors
  • WIPO sectorElectrical engineering

Abstract

A method of forming a copper interconnect in a dual damascene scheme is described. After a diffusion barrier layer and seed layer are sequentially formed on the sidewalls and bottoms of a trench and via in a dielectric layer, a first copper layer is deposited by a first ECP process at a 10 mA/cm2 current density to fill the via and part of the trench. A first anneal step is performed to remove carbon impurities and optionally includes a H2 plasma treatment. A second ECP process with a first deposition step at a 40 mA/cm2 current density and second deposition step at a 60 mA/cm2 current density is used to deposit a second copper layer-that overfills the trench. After a second anneal step, a CMP process planarizes the copper layers. Fewer copper defects, reduced S, Cl, and C impurities, and improved Rc performance are achieved by this method.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.