Patent · US Expired

Chemical vapor deposition of niobium barriers for copper metallization

US6475902B1 · kind B1 · utility

327Cited by
5References
20Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMar 10, 2000
Grant dateNov 5, 2002
Priority date
Expiry dateMar 10, 2020

Classification

  • Technology area (CPC H)Electricity
  • CPC primaryH01L21/76874
  • WIPO fieldSemiconductors
  • WIPO sectorElectrical engineering

Abstract

A method of depositing a metal nitride material, formed by the decomposition of an organometallic precursor, useful as a barrier layer for an integrated circuit using a conducting metal. More particularly, the invention provides a method of depositing a niobium nitride layer on a substrate for use in copper metallization. In one aspect of the invention an organometallic precursor having the formula Nb(NRR′)5, the formula (NRR′)3Nb═NR″, or combinations thereof, is introduced into a processing chamber in the presence of a processing gas, such as ammonia, and the metal nitride film is deposited by the thermal or plasma enhanced decomposition of the precursor on a substrate. The deposited niobium nitride layer is then exposed to a plasma to remove contaminants, reduce the film's resistivity, and densify the film.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.