Patent · US Expired

Interlayer oxide containing thin films for high dielectric constant application

US6495878B1 · kind B1 · utility

37Cited by
15References
36Claims
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Key dates

Filing dateAug 2, 1999
Grant dateDec 17, 2002
Priority date
Expiry dateAug 2, 2019

Classification

  • Technology area (CPC H)Electricity
  • CPC primaryH01L21/02282
  • WIPO fieldSemiconductors
  • WIPO sectorElectrical engineering

Abstract

A high dielectric constant insulator including a thin film of a metal oxide selected from the group consisting of tungsten-bronze-type oxides, pyrochlore-type oxides, and combinations of Bi2O3 with an oxide selected from the group consisting of perovskites and pyrochlore-type oxides. An embodiment contains metal oxides represented by the general stoichiometric formulas AB2O6, A2B2O7 and A2Bi2B2O10, wherein A represents A-site atoms selected from the group of metals consisting of Ba, Bi, Sr, Pb, Ca, K, Na and La; and B represents B-site atoms selected from the group of metals consisting of Ti, Zr, Ta, Hf, Mo, W and Nb. Preferably, the metal oxides are (BaxSr1&#8722;x)(TayNb1&#8722;y)2O6, where 0&lE;x&lE;1.0 and 0&lE;y&lE;1.0; (BaxSr1&#8722;x)2(TayNb1&#8722;Y)2O7, where 0&lE;x&lE;1.0 and 0&lE;y&lE;1.0; and (BaxSr1&#8722;x)2Bi2(TayNb1&#8722;y)2O10, where 0&lE;x&lE;1.0 and 0&lE;y&lE;1.0. Thin films according to the invention have a relative dielectric constant &gE;40, and preferably about 100. The value of Vcc in the metal oxides of the invention is close to zero. The value of Tcc is <1000 ppm, preferably <100.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.