Patent · US Expired

Plasma curing of MSQ-based porous low-k film materials

US6759098B2 · kind B2 · utility

545Cited by
45References
19Claims
0Family size

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Key dates

Filing dateJul 16, 2001
Grant dateJul 6, 2004
Priority date
Expiry dateJul 16, 2021

Classification

  • Technology area (CPC H)Electricity
  • CPC primaryH01L21/02282
  • WIPO fieldSemiconductors
  • WIPO sectorElectrical engineering

Abstract

Low dielectric constant film materials with improved elastic modulus. The method of making such film materials involves providing a porous methyl silsesquioxane based dielectric film material produced from a resin molecule containing at least 2 Si—CH3 groups and plasma curing the porous film material to convert the film into porous silica. Plasma curing of the porous film material yields a film with improved modulus and outgassing properties. The improvement in elastic modulus is typically greater than or about 100%, and more typically greater than or about 200%. The plasma cured porous film material can optionally be annealed. The annealing of the plasma cured film may reduce the dielectric constant of the film while maintaining an improved elastic modulus as compared to the plasma cured porous film material. The annealed, plasma cured film has a dielectric constant between about 1.1 and about 2.4 and an improved elastic modulus.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.