Methods and apparatus for selective deposition of cobalt in semiconductor processing
US9153482B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Feb 3, 2014 |
| Grant date | Oct 6, 2015 |
| Priority date | — |
| Expiry date | Feb 3, 2034 |
Classification
- Technology area (CPC H)Electricity
- CPC primaryH01L2924/0002
- WIPO fieldSemiconductors
- WIPO sectorElectrical engineering
Abstract
Methods and apparatus for selective deposition of cobalt on copper lines in the presence of exposed dielectric in semiconductor processing are provided. Cobalt in its metallic form is selectively deposited onto copper in the presence of dielectric by contacting a prepared surface of the substrate with an organometallic cobalt compound in a presence of a reducing agent. Surface preparation involves H2 treatment with concurrent UV light irradiation. After the substrate surface is prepared, the substrate is contacted with an organometallic cobalt compound comprising a substituted or unsubstituted allyl ligand in a presence of a reducing agent to selectively deposit cobalt on copper. No plasma treatment during or after cobalt deposition is necessary, and the method can be used in a presence of a ULK dielectric without causing damage to dielectric. Deposited cobalt caps are used to reduce copper electromigration and to improve adhesion of copper to subsequently deposited layers.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.