Patent · US Expired

Atomic layer-deposited hafnium aluminum oxide

US7135421B2 · kind B2 · utility

632Cited by
106References
61Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 5, 2002
Grant dateNov 14, 2006
Priority date
Expiry dateNov 29, 2022

Classification

  • Technology area (CPC H)Electricity
  • CPC primaryH10D64/693
  • WIPO fieldSemiconductors
  • WIPO sectorElectrical engineering

Abstract

A dielectric film containing HfAlO3 and a method of fabricating such a dielectric film produce a reliable gate dielectric having an equivalent oxide thickness thinner than attainable using SiO2. A gate dielectric is formed by atomic layer deposition employing a hafnium sequence and an aluminum sequence. The hafnium sequence uses HfCl4 and water vapor. The aluminum sequence uses either trimethylaluminum, Al(CH3)3, or DMEAA, an adduct of alane (AlH3) and dimethylethylamine [N(CH3)2(C2H5)], with distilled water vapor. These gate dielectrics containing a HfAlO3 film are thermodynamically stable such that the HfAlO3 film will have minimal reactions with a silicon substrate or other structures during processing.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.