Patent · US Expired

Method of porogen removal from porous low-k films using UV radiation

US7208389B1 · kind B1 · utility

558Cited by
51References
38Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 26, 2003
Grant dateApr 24, 2007
Priority date
Expiry dateSep 26, 2023

Classification

  • Technology area (CPC H)Electricity
  • CPC primaryH01L21/02274
  • WIPO fieldSemiconductors
  • WIPO sectorElectrical engineering

Abstract

Methods of preparing a porous low-k dielectric material on a substrate are provided. The methods involve the use of ultraviolet radiation to react with and remove porogen from a porogen containing precursor film, leaving a porous low-k dielectric matrix. Methods using oxidative conditions and non-oxidative conditions are described. The methods described may be used to remove porogen from porogen-containing precursor films. The porogen may be a hydrocarbon such as a terpene (e.g., alpha-terpinene) or a norbornene (e.g., ENB). The resulting porous low-k dielectric matrix can then be annealed to remove water and remaining silanols capped to protect it from degradation by ambient conditions, which methods will also be described.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.